| 158 | GJ Maxwell (115) & H Riazuddin (60*) | Hampshire Second XI v Marylebone Cricket Club Young Cricketers | Denis Compton Oval, Shenley | 2012 |
| 151* | OJ Price (100*) & TJ Price (88*) | Gloucestershire Second XI v Worcestershire Second XI | College Ground, Cheltenham | 2022 |
| 151 | MJJ Critchley (73*) & PI Walter (78) | Essex Second XI v Kent Second XI | The Cloud County Ground, Chelmsford | 2023 |
| 146* | AP Beard (75*) & OM Akram (60*) | Essex Second XI v Middlesex Second XI | Tivoli Road, Hornsey | 2023 |
| 138 | CT Bancroft (92*) & SR Dickson (66) | Durham Second XI v Nottinghamshire Second XI | Emirates Riverside, Chester-le-Street | 2021 |
| 129 | TA Wood (91) & D Smit (62) | Derbyshire Second XI v Leicestershire Second XI | The Copper Yard, Denby Village | 2018 |
| 128 | LJ Wright (104) & BC Brown (64) | Sussex Second XI v Hampshire Second XI | Blackstone Cricket Club Ground, Blackstone | 2019 |
| 125 | FIN Khushi (69) & AP Beard (50) | Essex Second XI v Somerset Second XI | The Cloudfm County Ground, Chelmsford | 2017 |
| 125 | WMH Rhodes (43) & MJ Lamb (80) | Warwickshire Second XI v Leicestershire Second XI | Park Road, Loughborough | 2018 |
| 124 | JB Cracknell (98) & BC Cullen (62*) | Middlesex Second XI v Kent Second XI | Polo Farm Sports Club, Canterbury | 2025 |
| 123 | GFB Scott (66) & NRT Gubbins (66*) | Middlesex Second XI v Essex Second XI | Merchant Taylors' School Ground, Northwood | 2019 |
| 121 | JLB Davies (87*) & RG White (53) | Middlesex Second XI v Sussex Second XI | Cricket Field Road, Horsham | 2023 |
| 120 | RP Jones (49*) & HJ Cullen (79) | Worcestershire Second XI v Gloucestershire Second XI | Main Road, Ombersley | 2025 |
| 119 | JJ Cobb (78*) & WD Parnell (49) | Northamptonshire Second XI v Gloucestershire Second XI | County Ground, Bristol | 2021 |
| 119 | RS Bopara (144) & GHS Garton (53) | Sussex Second XI v Middlesex Second XI | Old Deer Park, Richmond | 2023 |
| 116 | JEK Rew (69) & GW Thomas (60) | Somerset Second XI v Gloucestershire Second XI | College Ground, Cheltenham | 2022 |
| 116* | TR Bevan (132*) & WT Root (44*) | Glamorgan Second XI v Middlesex Second XI | Arundel Castle Cricket Club Ground, Arundel | 2022 |
| 114* | CS MacLeod (103*) & GJ Muchall (32*) | Durham Second XI v Yorkshire Second XI | Clifton Park, York | 2014 |
| 113 | JJ Weatherley (62) & AST West (54) | Hampshire Second XI v Surrey Second XI | The Ridge, Purley | 2016 |
| 110 | JA Leaning (52) & WMH Rhodes (39) | Yorkshire Second XI v Durham Second XI | Clifton Park, York | 2014 |
| 108* | GJ Muchall (61*) & SG Borthwick (31*) | Durham Second XI v Lancashire Second XI | Roseworth Terrace, Gosforth | 2012 |
| 108* | DP Sibley (102*) & MJ Lamb (48*) | Warwickshire Second XI v Leicestershire Second XI | Park Road, Loughborough | 2018 |
| 108* | AO Morgan (72*) & TN Cullen (38*) | Glamorgan Second XI v Unicorns | Tunstall Road, Knypersley | 2018 |
| 108* | BJ Dawkins (108*) & CL Flintoff (39*) | Kent Second XI v Essex Second XI | The Kent County Cricket Ground, Beckenham | 2025 |
| 107* | AWR Barrow (56*) & JH Davey (50*) | Somerset Second XI v Gloucestershire Second XI | Taunton Vale Sports Club Ground, Taunton | 2015 |
| 107 | LC Paternott (76) & S Prasanna (71) | Northamptonshire Second XI v Leicestershire Second XI | Bedford School Ground, Bedford | 2016 |
| 107 | WJ Weighell (84) & RC Davies (29) | Durham Second XI v Marylebone Cricket Club Young Cricketers | Roseworth Terrace, Gosforth | 2018 |
| 106* | TC Lace (73*) & NA Sowter (69*) | Middlesex Second XI v Surrey Second XI | London School of Economics Sports Ground, New Malden | 2018 |
| 104 | AJ Hose (67*) & SS McKechnie (34) | Marylebone Cricket Club Young Cricketers v Sussex Second XI | Denis Compton Oval, Shenley | 2013 |
| 103 | MNW Spriegel (65*) & A Harinath (56) | Surrey Second XI v Hampshire Second XI | The Ageas Bowl, Southampton | 2012 |
| 100 | RP Jones (85*) & KN Watson (50) | Lancashire Second XI v Yorkshire Second XI | Stanley Park, Blackpool | 2022 |
