| 171 | AJ Hose (119) & DR Mousley (58*) | Warwickshire v Northamptonshire | Edgbaston, Birmingham | 2020 |
| 139* | JA Simpson (53*) & TP Alsop (87*) | Sussex v Kent | Spitfire Ground, St Lawrence, Canterbury | 2024 |
| 124 | GD Phillips (94*) & JMR Taylor (38) | Gloucestershire v Sussex | The 1st Central County Ground, Hove | 2021 |
| 123 | JA Leaning (64) & JM Cox (64) | Kent v Middlesex | Spitfire Ground, St Lawrence, Canterbury | 2021 |
| 117 | M van Jaarsveld (75) & MJ Walker (38*) | Kent v Leicestershire | Grace Road, Leicester | 2006 |
| 117* | MNW Spriegel (53*) & GC Wilson (54*) | Surrey v Middlesex | Lord's Cricket Ground, St John's Wood | 2012 |
| 117* | RN ten Doeschate (55*) & RS Bopara (70*) | Essex v Surrey | The Kia Oval, Kennington | 2019 |
| 114* | HG Kuhn (54*) & AJ Blake (66*) | Kent v Middlesex | Lord's Cricket Ground, St John's Wood | 2019 |
| 110* | RA White (94*) & N Boje (27*) | Northamptonshire v Gloucestershire | Campbell Park, Milton Keynes | 2008 |
| 109 | DI Stevens (90) & AJ Blake (27) | Kent v Surrey | The Kia Oval, Kennington | 2015 |
| 109 | CN Ackermann (56) & RK Patel (57) | Leicestershire v Yorkshire | Headingley, Leeds | 2022 |
| 109 | SW Billings (106) & JL Denly (32) | Kent v Somerset | Spitfire Ground, St Lawrence, Canterbury | 2024 |
| 107 | GJ Maxwell (73) & DJ Vilas (46) | Lancashire v Nottinghamshire | Emirates Old Trafford, Manchester | 2019 |
| 106 | SB Styris (56) & EJG Morgan (66) | Middlesex v Surrey | Lord's Cricket Ground, St John's Wood | 2006 |
| 106* | DL Hemp (60*) & JEC Franklin (69*) | Glamorgan v Warwickshire | Edgbaston, Birmingham | 2006 |
| 106* | BM Duckett (92*) & SP Crook (34*) | Northamptonshire v Worcestershire | County Ground, New Road, Worcester | 2017 |
| 104 | PD Trego (70) & CJ Anderson (53) | Somerset v Surrey | The Cooper Associates County Ground, Taunton | 2018 |
| 103 | WI Jefferson (75) & CMW Read (43*) | Nottinghamshire v Durham | Trent Bridge, Nottingham | 2009 |
| 103 | ID Blackwell (59) & DM Benkenstein (53) | Durham v Nottinghamshire | Trent Bridge, Nottingham | 2009 |
| 101* | DA Leatherdale (52*) & AJ Bichel (37*) | Worcestershire v Somerset | County Ground, Taunton | 2004 |
| 101* | CL White (141*) & JC Hildreth (27*) | Somerset v Worcestershire | County Ground, New Road, Worcester | 2006 |
| 101 | JLB Davies (53) & MK Andersson (52) | Middlesex v Gloucestershire | College Ground, Cheltenham | 2024 |
| 100* | AJ Hose (63*) & CG Benjamin (58*) | Warwickshire v Northamptonshire | County Ground, Northampton | 2022 |
