| 141* | HC Brook (83*) & JA Thompson (66*) | Yorkshire v Worcestershire | Emerald Headingley Cricket Stadium, Leeds | 2021 |
| 129* | SA Abbott (110*) & J Clark (29*) | Surrey v Kent | The Kia Oval, Kennington | 2023 |
| 126* | CS MacLeod (64*) & JW Hastings (80*) | Durham v Northamptonshire | Emirates Durham International Cricket Ground, Chester-le-Street | 2014 |
| 121* | MS Pepper (120*) & CWJ Allison (44*) | Essex v Sussex | The 1st Central County Ground, Hove | 2024 |
| 114 | SJ Mullaney (79) & DT Christian (56) | Nottinghamshire v Yorkshire | Headingley, Leeds | 2022 |
| 108* | SA Northeast (60*) & AJ Blake (71*) | Kent v Hampshire | The Ageas Bowl, Southampton | 2015 |
| 106* | SR Hain (83*) & CR Brathwaite (52*) | Warwickshire v Worcestershire | Edgbaston, Birmingham | 2021 |
| 102* | A Javid (15*) & Mohammad Nabi (86*) | Leicestershire v Lancashire | Emirates Old Trafford, Manchester | 2018 |
| 98* | RWT Key (41*) & MJ Walker (58*) | Kent v Middlesex | The Kent County Cricket Ground, Beckenham | 2006 |
| 96* | L Gregory (57*) & BGF Green (35*) | Somerset v Nottinghamshire | The Cooper Associates County Ground, Taunton | 2023 |
| 95* | WT Root (38*) & DA Douthwaite (51*) | Glamorgan v Kent | Spitfire Ground, St Lawrence, Canterbury | 2022 |
| 93 | RN ten Doeschate (49*) & JD Middlebrook (43) | Essex v Sussex | The Ford County Ground, Chelmsford | 2006 |
| 91 | DJ Vilas (40) & R McLaren (77) | Lancashire v Northamptonshire | County Ground, Northampton | 2017 |
| 91 | KS Carlson (71) & T van der Gugten (48) | Glamorgan v Somerset | Sophia Gardens, Cardiff | 2023 |
| 90* | MR Ramprakash (76*) & AJ Hollioake (44*) | Surrey v Hampshire | The Brit Oval, Kennington | 2004 |
| 90 | CJ Anderson (41*) & L Gregory (62) | Somerset v Middlesex | The Cooper Associates County Ground, Taunton | 2018 |
| 89 | CN Ackermann (74) & EJH Eckersley (39*) | Leicestershire v Durham | Emirates Riverside, Chester-le-Street | 2018 |
| 89 | TA Lammonby (90) & RE van der Merwe (5) | Somerset v Gloucestershire | The Cooper Associates County Ground, Taunton | 2021 |
| 88* | JK Fuller (53*) & IG Holland (36*) | Hampshire v Sussex | The 1st Central County Ground, Hove | 2020 |
| 88 | T Banton (77*) & BGF Green (47) | Somerset v Gloucestershire | The Cooper Associates County Ground, Taunton | 2024 |
| 86 | OB Cox (28) & RA Whiteley (89*) | Worcestershire v Lancashire | Blackfinch New Road, Worcester | 2019 |
| 86 | CWJ Allison (69*) & LM Benkenstein (54) | Essex v Hampshire | Utilita Bowl, Southampton | 2024 |
| 85* | Azhar Mahmood (65*) & SA Newman (20*) | Surrey v Hampshire | The Rose Bowl, Southampton | 2006 |
| 85 | LPJ Kimber (53) & OB Cox (55) | Leicestershire v Worcestershire | Visit Worcestershire New Road, Worcester | 2024 |
| 84* | DL Hemp (68*) & BJ Wright (35*) | Glamorgan v Somerset | County Ground, Taunton | 2007 |
| 83* | IJ Westwood (49*) & AG Botha (35*) | Warwickshire v Somerset | County Ground, Taunton | 2009 |
| 82* | DJG Sales (78*) & DG Wright (38*) | Northamptonshire v Gloucestershire | Campbell Park, Milton Keynes | 2005 |
| 82* | GT Park (50*) & RA Whiteley (39*) | Derbyshire v Northamptonshire | County Ground, Derby | 2011 |
| 82 | DJ Bell-Drummond (89) & JM Cox (39*) | Kent v Middlesex | Spitfire Ground, St Lawrence, Canterbury | 2020 |
| 82* | BG Charlesworth (36*) & OJ Price (43*) | Gloucestershire v Somerset | Seat Unique Stadium, Bristol | 2024 |
| 81* | MH Yardy (68*) & CD Hopkinson (22*) | Sussex v Surrey | The Brit Oval, Kennington | 2006 |
| 81* | TB Abell (46*) & L Gregory (60*) | Somerset v Nottinghamshire | The Cooper Associates County Ground, Taunton | 2018 |
| 80 | SR Hain (93) & GHS Garton (29*) | Warwickshire v Northamptonshire | County Ground, Northampton | 2024 |
